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Submissions from 2003

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catena-Poly[1-methylpiperazinium [[aquadioxouranium(VI)]-di-- sulfato-4O:O']], Clair L. Stuart, Michael B. Doran, Alexander J. Norquist, and Dermot O'Hare

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Organically templated uranium(VI) sulfates: understanding phase stability using composition space, Paul M. Thomas, Alexander J. Norquist, Michael B. Doran, and Dermot O'Hare

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The Formation of Ordered Heterostructures During the Intercalation of Phosphonic Acids into a Layered Double Hydroxide, G. R. Williams, Alexander J. Norquist, and Dermot O'Hare

Submissions from 2002

Explorations in Physical Chemistry: a Resource for Users of Mathcad, P. W. Atkins and Julio C. de Paula

Physical Chemistry (7th ed.), P. W. Atkins and Julio C. de Paula

Calbindin D-28k Exhibits properties characteristic of a Ca2+ sensor, T. Berggard, S. Miron, P. Onnerfjord, and Karin S. Akerfeldt

Rotational spectroscopy of DNO3, S. Grace Chou, Douglas T. Petkie, Rebecca A.H. Butler, and Charles E. Miller

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[NC4H12]2 [(UO2)6(H2O)2(SO4)7]: the first organically templated actinide sulfate with a three-dimensional framework structure, Michael B. Doran, Alexander J. Norquist, and Dermot O'Hare

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The first organically templated thorium compounds, [C4N2H12]0.5[ThF5] and [C5N2H14] [ThF6]-0.5H20, Jong-Young Kim, Alexander J. Norquist, and Dermot O'Hare

Solvent dynamical control of electon-transfer rathes in mixed-valence complexes observed by infrared spectral line shape coalescence, Casey H. Londergan, J. Catherine Salsman, S. Ronco, and L. M. Dolkas

A quadratic configuration interaction study of the proton affinity of acetic acid, Charles E. Miller and Joseph S. Francisco

Synthesis of Cyclical Diamine Templated Uranium Sulfates, Alexander J. Norquist, Paul M. Thomas, Michael B. Doran, and Dermot O'Hare

The West Falmouth oil spill after thirty years: The persistence of petroleum hydrocarbons in marsh sediments, C. M. Reddy, T. I. Eglinton, A. H. Hounshell, and Helen K. White

The First Example of a Nitrile Hydratase Model Complex that Reversibly Binds Nitriles, J. Shearer, H. L. Jackson, D. Schweitzer, and Robert C. Scarrow

Synthetic Models For the Cysteinate-Ligated Non-Heme Iron Enzyme Superoxide Reductase: Observation and Structural Characterization by XAS of an FeIII-OOH Intermediate, J. Shearer, Robert C. Scarrow, and J. A. Kovacs

In‐Situ time‐resolved X‐ray diffraction: The current state of the art, Anne E. Terry, Gavin B.M. Vaughn, and Alexander J. Norquist

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Recent results from the in situ study of hydrothermal crystallizations using time-resolved X-ray and neutron diffraction methods, Richard I. Walton, Alexander J. Norquist, Ronald I. Smith, and Dermot O'Hare

Crystal-growth and co-substitution in (Mg1-xFex) (Mo2-xVx)O7 (0.13, Xiandong Wang, Alexander J. Norquist, Jason Pless, and Charlotte L. Stern

Synthesis and Ion Conductance Behavior of a Tetrameric Alamethicin Ion Channel, Ari Wassner '00, Jessica A. Hurt '99, James D. Lear, and Karin S. Akerfeldt

Out-of-Center Distortions in d0 Transition Metal Oxide Fluoride Anions, Margaret E. Welk, Alexander J. Norquist, Frederick P. Arnold, and Charlotte L. Stern

Post-depositional transport and fate of PAHs 30 years after the West Falmouth oil spill, Helen K. White, C. M. Reddy, T. I. Eglinton, and A. L. Lima

Submissions from 2001

Not just for grad schools anymore, Julio C. de Paula

Further Investigations of the ClO Rotational Spectrum, Brian J. Drouin, Charles E. Miller, Edward A. Cohen, and Georg Wagner

The rotational spectra, and X-2 (2)Pi(1/2) states of BrO, Brian J. Drouin, Charles E. Miller, J. S.P. Muller, and Edward A. Cohen

Absence of Ligand-Mediated Symmetry Reduction in a Solid Solution: Cu(NC5H5)4 [(NbOF5)1-x(WO2F4)x] (0, Kevin R. Heier, Alexander J. Norquist, Claude L. Mertzenich, and Kenneth R. Poeppelmeier

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Intercalculation and controlled release of pharmaceutically active compounds from a layered double hydroxide, Aamir I. Khan, Lixu Lei, Alexander J. Norquist, and Dermot O'Hare

Characterization of the O2-Evolving reaction catalyzed by [(terpy)(H2O)MnIII(O)2MnIV(OH2)(terpy)](NO3)3 (terpy = 2,2':6,2''-Terpyridine), J. Limburg, J. S. Vrettos, H. Chen, and Julio C. de Paula

High-frequency EPR study of a new mononuclear manganese(III) complex: [(terpy)Mn(N3)3] (terpy = 2,2':6',2''-Terpyridine), J. Limburg, J. S. Vrettos, R. H. Crabtree, and Julio C. de Paula

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Rotational spectroscopy of IO X2-pi-i, Charles E. Miller and Edward A. Cohen

The X-1(2)Pi(3/2) and X-2(2)Pi(1/2) potential energy surfaces of FO, Charles E. Miller and Brian J. Drouin

Proton affinity of peroxyacetyl nitrate (PBN), Charles E. Miller and Joseph S. Francisco

Symmetry breaking and the molecular structure of NO3+, Charles E. Miller and Joseph S. Francisco

The formation of a surprisingly stable HO2-H2SO4 complex, Charles E. Miller and Joseph S. Francisco

Polar Compounds Constructed with the [Cr2O7]2- Anion, Alexander J. Norquist, Kevin R. Heier, P. Shiv Halasyamani, and Charlotte L. Stern

Immobilized Metal Complexes in Porous Organic Hosts, Karen M. Padden, John F. Krebs, Cora E. Mac Beth, and Robert C. Scarrow

Probing the Structure of Immobilized Metal Sites in Porous Organic Hosts by X-ray Absorption Spectroscopy, K. M. Padden, J. F. Krebs, K. T. Trafford, and Robert C. Scarrow

Interactions of copper(II) porphyrins with DNA, R. F. Pasternack, E. J. Gibbs, P. J. Collings, and Julio C. de Paula

Factors that determine the unusually low reduction potential of cytochrome c550 in cyanobacterial photosystem II, J. S. Vrettos, M. J. Reifler, O. Kievit, and Julio C. de Paula

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Direct in situ observation of increasing structural dimensionality during the hydrothermal formation of open-framework zinc phosphates, Richard I. Walton, Alexander J. Norquist, S. Neeraj, and Srinivasan Natarajan

The Ordered [WO2F4]2- Anion, Margaret E. Welk, Alexander J. Norquist, Charlotte L. Stern, and Kenneth R. Poeppelmeier

Tracing the fate of organic contaminants in the environment using natural radiocarbon abundance, Helen K. White, C. M. Reddy, T. I. Eglinton, and J. M. Hayes

Submissions from 2000

Fragment complementation of Calbindin D28k, Tord Berggard, Eva Thulin, Karin S. Akerfeldt, and Sara Linse

Organization of bacteriochlorophyll aggregates and carotenoids in bacterial chlorosomes studied by resonance light scattering spectroscopy, Julio C. de Paula, P. Parkash, J. H. Robblee, and J. Agnew

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The HCO2 potential energy surface: Stationary point energetics and the HOCO heat of formation, Timothy V. Duncan '00 and Charles E. Miller

Porphobilinogen Synthase from Pea: Expression from an artificial gene, kinetic characterization, and novel implications for subunit interactions, Jukka Kervinen, Roland L. Dunbrack Jr., Samuel Litwin, and Robert C. Scarrow

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Photo-induced isotopic fractionation, Charles E. Miller and Yuk L. Yung

Synthesis of the Neutral (CuF(NC5H5)4)2NbOF5 Cluster, Alexander J. Norquist, Margaret E. Welk, Charlotte L. Stern, and Kenneth R. Poeppelmeier

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Aggregation kinetics of extended porphyrin and cyanine dye assemblies, R. F. Pasternack, C. Fleming, S. Herring, and Julio C. de Paula

The g-Factor Anisotropy of Plant Chlorophyll a•+, Joshua Schrier, P. J. Pratt, O. G. Poluektov, and M. C. Thurnauer

The Structure-Directing Properties of [VOF5]2-, Margaret E. Welk, Alexander J. Norquist, Charlotte L. Stern, and Kenneth R. Poeppelmeier

Submissions from 1999

Maxfield Parrish: the artist when chemist, John P. Chesick

The Polar [WO2F4]2- Anion in the Solid State, Kevin R. Heier, Alexander J. Norquist, P. Shiv Halasyamani, and Angel Duarte

Electron paramagnetic resonance studies of manganese toxicity, tolerance, and amelioration with silicon in snapbean, E. I. Jücker, C. D. Foy, Julio C. de Paula, and J. Centeno

Cu(C10H9N3) 2MOF5-2H2O (M=Nb, Ta): Aligned [MOF5]2- Oxide Fluoride Anions, Alexander J. Norquist, Charlotte L. Stern, and Kenneth R. Poeppelmeier

Tremorgenic indole alkaloids: studies directed toward the assembly of the A, F, and I rings of Penitrem D : observation of an unexpected stereochemical outcome, Amos B. Smith III, N. Kanoh, N. Minakawa, and Frances Rose Blase

Low-temperature optical and resonance Raman spectra of a carotenoid cation radical in photosystem II, J. S. Vrettos, D. H. Stewart, Julio C. de Paula, and Gary W. Brudvig

Protonation of porphyrin in iron-free cytochrome c: spectral properties of monocation free base porphyrin, a charge analogue of ferric heme, Suzanne Zentko '98, Robert C. Scarrow, Wayne W. Wright, and J. M. Vanderkooi

Submissions from 1998

Composition Space of the (CdO, 0.5Nb2O5)/ (HF)x-Pyridine/H2O System. Structure and Synthesis of CdNb(py)4OF5, P. Shiv Halasyamani, Kevin R. Heier, Alexander J. Norquist, and Charlotte L. Stern

[pyH]2[Cu(py)4(MX6)2] (MX6=ZrF62-, NbOF52-; MoO2F42-; py=Pyridine): Rarely Observed Ordering of Metal Oxide Fluoride Anions, Kevin R. Heier, Alexander J. Norquist, Christopher G. Stern, and Charlotte L. Stern

Dynamic model of hormonal systems coupled by negative feedback , Casey H. Londergan and Enrique Peacock-López

Composition Space Diagrams for Mixed Transition Metal Oxide Fluorides, Alexander J. Norquist, Kevin R. Heier, Charlotte L. Stern, and Kenneth R. Poeppelmeier

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Depolarized resonance light scattering by porphyrin and chlorophyll a aggregates, Jai Parkash, John H. Robblee, John Agnew, and Julio C. de Paula

Non-conventional approach to supramolecular formation dynamics: the kinetics of assembly of DNA-bound porphyrins, R. F. Pasternack, E. J. Gibbs, P. J. Collings, and Julio C. de Paula

X-ray Spectroscopy of Nitric Oxide Binding to Iron in Inactive Nitrile Hydratase and a Synthetic Model Compound, Robert C. Scarrow, Brent S. Stickler, Jeffrey J. Ellison, and Steven C. Shoner

Submissions from 1997

Synthetic peptide as models for ion channel proteins, Karin S. Akerfeldt, James D. Lear, and William F. DeGrado

Synthesis, transient absorption, and transient resonance raman spectroscopy of novel electron donor-acceptor complexes: [5,15-Bis[(4'-nitrophenyl)ethynyl]-10,20-diphenylporphinato]copper(II) and [5-[[4'-(Dimethylamino)phenyl]ethynyl]-15-[(4''-nitrophenyl)ethynyl]-10,20-diphenylporphinato]copper(II), S. M. LeCours, C. M. Philips, Julio C. de Paula, and M. J. Therien

Domain organization of Calbindin D28k as determined from the association of six synthetic EF-hand fragments, S. Linse, E. Thulin, L. K. Gifford, and Karin S. Akerfeldt

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The OBrO C(2A2)←X(2B1) absorption spectrum, Charles E. Miller, Scott L. Nickolaisen, Joseph S. Francisco, and Stanley P. Sander

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The rotational spectrum and molecular properties of bromine dioxide, OBrO, Holger S. P. Muller, Charles E. Miller, and Edward A. Cohen

Synthesis, characterization, and luminescence properties of anthrylpolyamines: an experiment for an integrated, advanced laboratory course, Brian W. Pfennig, Terry L. Newirth, and Scott A. Van Arman

Submissions from 1996

Ca2+-binding stoichiometry of Calbindin D28k as assessed by spectroscopic analyses of synthetic peptide fragments, Karin S. Akerfeldt, A. Coyne, R. R. Wilk, and E. Thulin

Structure and conductance mechanisms of minimalist ion channels, Karin S. Akerfeldt, Paul K. Kienker, and James D. Lear

Nitrile hydratase from Rhodococcus rhodochrous J1 contains a non-corrin cobalt ion with two sulfur ligands, Bridget A. Brennan, Geoffrey Alms, Mark J. Nelson, and Robert C. Scarrow

Protein folding triggered by electron transfer, G. A. Mines, T. Pascher, S. C. Lee, and John P. Chesick

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Pressure dependence and metastable state formation in the photolysis of dichlorine monoxide (Cl2O), Scott L. Nickolaisen, Charles E. Miller, Stanley P. Sander, and Michael R. Hand

Circular dichroism and x-ray spectroscopies of Azotobacter vinelandii nitrogenase iron protein. MgATP and MgADP induced protein conformational changes affecting the [4Fe-4S] cluster and characterization of a [2Fe-2S] form, Matthew J. Ryle, William N. Lanzilotta, Lance C. Seefeldt, and Robert C. Scarrow

X-ray spectroscopy of nitrile hydratase at pH 7 and 9, Robert C. Scarrow, Bridget A. Brennan, John G. Cummings, and Haiyong Jin

Submissions from 1995

Ullmann ether reaction involving an alkynyl substrate: a convergent route to a combretastatin intermediate, Frances Rose Blase and Kaustuv Banerjee '92

Synthesis of alpha-unsubstituted aldol adducts utilizing enantiomerically pure beta-keto delta-dioxolane sulfoxides, Frances Rose Blase and H. Le

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Aggregation of chlorophyll a probed by resonance light scattering spectroscopy, Julio C. de Paula, J. H. Robblee, and R. F. Pasternack

Transient resonance Raman spectroscopy of copper(II) complexes of meso-tetraphenylporphine and meso-tetraphenylchlorin, Julio C. de Paula, V. A. Walters, K. Hall, and J. Lind

Structure and Kinetics of Formation of Catechol Complexes of ferric soybean lipoxygenase-1, Mark J. Nelson, Bridget A. Brennan, D. Bruce Chase, and Robert C. Scarrow

Acetylation of Ferrocene: a Study of the Friedel-Crafts Acylation Mechanism as Measured by HPLC using an Internal Standard, Terry L. Newirth and Nadine Srouji 92

Tremorgenic indole alkaloids. 9. asymmetric construction of an advanced F-G-H-ring lactone precursor for the synthesis of Penitrem D, Amos B. Smith III, Ernest G. Nolen Jr., R. Shirai, and Frances Rose Blase

Asymmetric construction of an advanced F-G-H-ring lactone precursor for the synthesis of penitrem D: tremorgenic indole alkaloids, part 9, Amos B. Smith III, Ernest G. Nolen Jr., Ryuichi Shirai, and Frances Rose Blase

Electronic structure of triplet states of zinc(II) tetraphenylporphyrins, V. A. Walters, Julio C. de Paula, B. Jackson, and C. Nutaitis

Submissions from 1994

Synthesis and per-functionalization of heptakis (6-O-carboxymethyl-2, 3-di-O-methyl) cyclomaltoheptaose, Karin S. Akerfeldt and William F. DeGrado

Use of cyanobacteria in the study of the structure and function of photosystem II, B. A. Barry, R. J. Boerner, and Julio C. de Paula

Spreadsheets in general chemistry: their introduction and application to complex titrations, John P. Chesick

General method for coupling unprotected peptides to Bromocetamido Porphyrin templates, Christin T. Choma, Karen Kaestle, and Karin S. Akerfeldt

Structure-function relationships in the 47-kDa antenna protein and its complex with the reaction center core of photosystem II: insights from resonance Raman spectroscopy and picosecond fluorescence decay kinetics, Julio C. de Paula, A. Liefshitz, S. Hinsley, and W. Lin

X-ray Spectroscopy of the Iron Site in Soybean Lipoxygenase-1: Changes in Coordination upon Oxidation or Addition of Methanol, Robert C. Scarrow, Milton G. Trimitsis, Charles P. Buck, and Geoffrey N. Grove

Submissions from 1993

Synthetic Peptides as Models for Ion Channel Proteins, Karin Akerfeldt, James D. Lear, Z. R. Wasserman, and L. A. Chung

Harmut Michel, Johann Deisenhofer, and Robert Huber, Julio C. de Paula

Three applications of a nitrogen laser pumped dye laser in the undergraduate laboratory: from spectroscopy to photochemistry, Julio C. de Paula, J. Lind, M. Gardner, and K. Walters

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Use of Near-Infrared Spectroscopy to Determine the Composition of High-Density/Low-Density Polyethylene Blend Films, Charles E. Miller

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Internal Energy Distributions from Nitrogen Dioxide Fluorescence 4. Variable-Wavelength Photodissociation of ClNO2 and HONO2, Charles E. Miller and Harold S. Johnston

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Nondestructive Characterizations of Polyethylene/Nylon Laminates by Near-Infrared Spectroscopy, Charles E. Miller, Svend A. Svensden, and Tormod Naes

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Infrared Emission Spectroscopy with Transient Cooling, Randy J. Pell, Charles E. Miller, Bruce R. Kowalski, and James B. Callis

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Difference-frequency generation in AgGaS2 by use of single-mode diode-laser pump sources, U. Simon, Charles E. Miller, C. C. Bradley, and R. G. Hulet