A Dihydroxo-Bridged Fe(II)-Fe(III) Complex: A New Member of the Diiron Diamond Core Family
Journal of the American Chemical Society
This paper used spectroscopic methods to determine that a compound synthesized by collaborator Christine McKenzie and her students has one iron in the +2 oxidation state and the other in the +3 state (rather than both having an oxidation state of +2.5). I was responsible for obtaining and interpreting the X-ray and near-IR spectra that were used to come to this conclusion. --author-supplied description
“A dihydroxo - bridged Fe(II) - Fe(III) complex: A new member of the diiron diamond core family.” Egdal, R. K.; Hazell, A.; Lar sen, F. B.; McKenzie, C. J.; Scarrow, R. C. J. Am. Chem. Soc. 2003 , 125 , 32 - 33.