Submissions from 2003
Time-Resolved, In-Situ Energy Dispersive X-ray Diffraction Studies of the Structural Transformations of Templated Zinc Phosphates Under Hydrothermal Conditions, Alexander J. Norquist and Dermot O'Hare
Kinetics and mechanism of decomposition of nickel benzyl complexes and determination of nickel-benzyl bond dissociation energies, Mark H. Schofield and Jack Halpern
Tight-binding g-factor calculations of CdSe nanostructures, Joshua Schrier and K. B. Whaley
Porphyrin nanorods, A. D. Schwab, Collin S. Rich '04, Julio C. de Paula, and Elizabeth R. Young '02
How does cyanide inhibit superoxide reductase?Insight from synthetic FeIIIN4S model complexes, J. Shearer, S. B. Fitch, W. Kaminsky, and Robert C. Scarrow
catena-Poly[1-methylpiperazinium [[aquadioxouranium(VI)]-di-- sulfato-4O:O']], Clair L. Stuart, Michael B. Doran, Alexander J. Norquist, and Dermot O'Hare
Organically templated uranium(VI) sulfates: understanding phase stability using composition space, Paul M. Thomas, Alexander J. Norquist, Michael B. Doran, and Dermot O'Hare
The Formation of Ordered Heterostructures During the Intercalation of Phosphonic Acids into a Layered Double Hydroxide, G. R. Williams, Alexander J. Norquist, and Dermot O'Hare
Submissions from 2002
Explorations in Physical Chemistry: a Resource for Users of Mathcad, Peter W. Atkins and Julio C. de Paula
Physical Chemistry (7th ed.), Peter W. Atkins and Julio C. de Paula
Calbindin D-28k Exhibits properties characteristic of a Ca2+ sensor, Tord Berggård, Simona Miron, Patrik Onnerfjord, and Karin S. Akerfeldt
Rotational spectroscopy of DNO3, S. Grace Chou, Douglas T. Petkie, Rebecca A.H. Butler, and Charles E. Miller
[NC4H12]2 [(UO2)6(H2O)2(SO4)7]: the first organically templated actinide sulfate with a three-dimensional framework structure, Michael B. Doran, Alexander J. Norquist, and Dermot O'Hare
The first organically templated thorium compounds, [C4N2H12]0.5[ThF5] and [C5N2H14] [ThF6]-0.5H20, Jong-Young Kim, Alexander J. Norquist, and Dermot O'Hare
Solvent dynamical control of electon-transfer rathes in mixed-valence complexes observed by infrared spectral line shape coalescence, Casey H. Londergan, J. Catherine Salsman, Silvia Ronco, and Laura M. Dolkas
A quadratic configuration interaction study of the proton affinity of acetic acid, Charles E. Miller and Joseph S. Francisco
Synthesis of Cyclical Diamine Templated Uranium Sulfates, Alexander J. Norquist, Paul M. Thomas, Michael B. Doran, and Dermot O'Hare
The West Falmouth oil spill after thirty years: The persistence of petroleum hydrocarbons in marsh sediments, Christopher M. Reddy, Timothy I. Eglinton, Aubrey H. Hounshell, and Helen K. White
The First Example of a Nitrile Hydratase Model Complex that Reversibly Binds Nitriles, J. Shearer, H. L. Jackson, D. Schweitzer, and Robert C. Scarrow
Synthetic Models For the Cysteinate-Ligated Non-Heme Iron Enzyme Superoxide Reductase: Observation and Structural Characterization by XAS of an FeIII-OOH Intermediate, J. Shearer, Robert C. Scarrow, and J. A. Kovacs
In‐Situ time‐resolved X‐ray diffraction: The current state of the art, Anne E. Terry, Gavin B.M. Vaughn, and Alexander J. Norquist
Recent results from the in situ study of hydrothermal crystallizations using time-resolved X-ray and neutron diffraction methods, Richard I. Walton, Alexander J. Norquist, Ronald I. Smith, and Dermot O'Hare
Crystal-growth and co-substitution in (Mg1-xFex) (Mo2-xVx)O7 (0.13, Xiandong Wang, Alexander J. Norquist, Jason Pless, and Charlotte L. Stern
Synthesis and Ion Conductance Behavior of a Tetrameric Alamethicin Ion Channel, Ari Wassner '00, Jessica A. Hurt '99, James D. Lear, and Karin S. Akerfeldt
Out-of-Center Distortions in d0 Transition Metal Oxide Fluoride Anions, Margaret E. Welk, Alexander J. Norquist, Frederick P. Arnold, and Charlotte L. Stern
Post-depositional transport and fate of PAHs 30 years after the West Falmouth oil spill, Helen K. White, Christopher M. Reddy, T. I. Eglinton, and Ana Lucía C. Lima
Submissions from 2001
Not just for grad schools anymore, Julio C. de Paula
Further Investigations of the ClO Rotational Spectrum, Brian J. Drouin, Charles E. Miller, Edward A. Cohen, and Georg Wagner
The rotational spectra, and X-2 (2)Pi(1/2) states of BrO, Brian J. Drouin, Charles E. Miller, J. S.P. Muller, and Edward A. Cohen
Absence of Ligand-Mediated Symmetry Reduction in a Solid Solution: Cu(NC5H5)4 [(NbOF5)1-x(WO2F4)x] (0, Kevin R. Heier, Alexander J. Norquist, Claude L. Mertzenich, and Kenneth R. Poeppelmeier
Intercalculation and controlled release of pharmaceutically active compounds from a layered double hydroxide, Aamir I. Khan, Lixu Lei, Alexander J. Norquist, and Dermot O'Hare
Characterization of the O2-Evolving reaction catalyzed by [(terpy)(H2O)MnIII(O)2MnIV(OH2)(terpy)](NO3)3 (terpy = 2,2':6,2''-Terpyridine), Julian Limburg, John S. Vrettos, Hongyu Chen, Julio C. de Paula, Robert H. Crabtree, and Gary W. Brudvig
High-frequency EPR study of a new mononuclear manganese(III) complex: [(terpy)Mn(N3)3] (terpy = 2,2':6',2''-Terpyridine), Julian Limburg, John S. Vrettos, Robert H. Crabtree, Gary W. Brudvig, and Julio C. de Paula
Rotational spectroscopy of IO X2-pi-i, Charles E. Miller and Edward A. Cohen
The X-1(2)Pi(3/2) and X-2(2)Pi(1/2) potential energy surfaces of FO, Charles E. Miller and Brian J. Drouin
Proton affinity of peroxyacetyl nitrate (PBN), Charles E. Miller and Joseph S. Francisco
Symmetry breaking and the molecular structure of NO3+, Charles E. Miller and Joseph S. Francisco
The formation of a surprisingly stable HO2-H2SO4 complex, Charles E. Miller and Joseph S. Francisco
Polar Compounds Constructed with the [Cr2O7]2- Anion, Alexander J. Norquist, Kevin R. Heier, P. Shiv Halasyamani, and Charlotte L. Stern
Immobilized Metal Complexes in Porous Organic Hosts, Karen M. Padden, John F. Krebs, Cora E. Mac Beth, and Robert C. Scarrow
Probing the Structure of Immobilized Metal Sites in Porous Organic Hosts by X-ray Absorption Spectroscopy, Karen M. Padden, John F. Krebs, K. T. Trafford, and Robert C. Scarrow
Interactions of copper(II) porphyrins with DNA, Robert F. Pasternack, Sean Ewens, Ashwin Rao, and Julio C. de Paula
Tracing the fate of organic contaminants in the environment using natural radiocarbon abundance, Christopher M. Reddy, Timothy I. Eglinton, Helen K. White, and John M. Hayes
Factors that determine the unusually low reduction potential of cytochrome c550 in cyanobacterial photosystem II, J. S. Vrettos, M. J. Reifler, O. Kievit, and Julio C. de Paula
Direct in situ observation of increasing structural dimensionality during the hydrothermal formation of open-framework zinc phosphates, Richard I. Walton, Alexander J. Norquist, S. Neeraj, and Srinivasan Natarajan
The Ordered [WO2F4]2- Anion, Margaret E. Welk, Alexander J. Norquist, Charlotte L. Stern, and Kenneth R. Poeppelmeier
Submissions from 2000
Fragment complementation of Calbindin D28k, Tord Berggård, Eva Thulin, Karin S. Akerfeldt, and Sara Linse
Organization of bacteriochlorophyll aggregates and carotenoids in bacterial chlorosomes studied by resonance light scattering spectroscopy, Julio C. de Paula, Jai Parkash, James H. Robblee, and John Agnew
The HCO2 potential energy surface: Stationary point energetics and the HOCO heat of formation, Timothy V. Duncan '00 and Charles E. Miller
Porphobilinogen Synthase from Pea: Expression from an artificial gene, kinetic characterization, and novel implications for subunit interactions, Jukka Kervinen, Roland L. Dunbrack Jr., Samuel Litwin, and Robert C. Scarrow
Photo-induced isotopic fractionation, Charles E. Miller and Yuk L. Yung
Synthesis of the Neutral (CuF(NC5H5)4)2NbOF5 Cluster, Alexander J. Norquist, Margaret E. Welk, Charlotte L. Stern, and Kenneth R. Poeppelmeier
Aggregation kinetics of extended porphyrin and cyanine dye assemblies, R. F. Pasternack, C. Fleming, S. Herring, and Julio C. de Paula
The g-Factor Anisotropy of Plant Chlorophyll a•+, Joshua Schrier, P. J. Pratt, O. G. Poluektov, and M. C. Thurnauer
The Structure-Directing Properties of [VOF5]2-, Margaret E. Welk, Alexander J. Norquist, Charlotte L. Stern, and Kenneth R. Poeppelmeier
Submissions from 1999
Maxfield Parrish: the artist when chemist, John P. Chesick
Electron paramagnetic resonance studies of manganese toxicity, tolerance, and amelioration with silicon in snapbean, Charles D. Foy, Julio C. de Paula, Jose A. Centeno, and Emilia Ivanova Jücker
The Polar [WO2F4]2- Anion in the Solid State, Kevin R. Heier, Alexander J. Norquist, P. Shiv Halasyamani, and Angel Duarte
Cu(C10H9N3) 2MOF5-2H2O (M=Nb, Ta): Aligned [MOF5]2- Oxide Fluoride Anions, Alexander J. Norquist, Charlotte L. Stern, and Kenneth R. Poeppelmeier
Tremorgenic indole alkaloids: studies directed toward the assembly of the A, F, and I rings of Penitrem D : observation of an unexpected stereochemical outcome, Amos B. Smith III, N. Kanoh, N. Minakawa, and Frances Rose Blase
Low-temperature optical and resonance Raman spectra of a carotenoid cation radical in photosystem II, J. S. Vrettos, D. H. Stewart, Julio C. de Paula, and Gary W. Brudvig
Protonation of porphyrin in iron-free cytochrome c: spectral properties of monocation free base porphyrin, a charge analogue of ferric heme, Suzanne Zentko '98, Robert C. Scarrow, Wayne W. Wright, and J. M. Vanderkooi
Submissions from 1998
Composition Space of the (CdO, 0.5Nb2O5)/ (HF)x-Pyridine/H2O System. Structure and Synthesis of CdNb(py)4OF5, P. Shiv Halasyamani, Kevin R. Heier, Alexander J. Norquist, and Charlotte L. Stern
[pyH]2[Cu(py)4(MX6)2] (MX6=ZrF62-, NbOF52-; MoO2F42-; py=Pyridine): Rarely Observed Ordering of Metal Oxide Fluoride Anions, Kevin R. Heier, Alexander J. Norquist, Christopher G. Stern, and Charlotte L. Stern
Dynamic model of hormonal systems coupled by negative feedback , Casey H. Londergan and Enrique Peacock-López
Composition Space Diagrams for Mixed Transition Metal Oxide Fluorides, Alexander J. Norquist, Kevin R. Heier, Charlotte L. Stern, and Kenneth R. Poeppelmeier
Depolarized resonance light scattering by porphyrin and chlorophyll a aggregates, Jai Parkash, John H. Robblee, John Agnew, and Julio C. de Paula
Non-conventional approach to supramolecular formation dynamics: the kinetics of assembly of DNA-bound porphyrins, Robert F. Pasternack, Esther J. Gibbs, Peter J. Collings, and Julio C. de Paula
X-ray Spectroscopy of Nitric Oxide Binding to Iron in Inactive Nitrile Hydratase and a Synthetic Model Compound, Robert C. Scarrow, Brent S. Stickler, Jeffrey J. Ellison, and Steven C. Shoner
Submissions from 1997
Synthetic peptide as models for ion channel proteins, Karin S. Akerfeldt, James D. Lear, and William F. DeGrado
Synthesis, transient absorption, and transient resonance raman spectroscopy of novel electron donor-acceptor complexes: [5,15-Bis[(4'-nitrophenyl)ethynyl]-10,20-diphenylporphinato]copper(II) and [5-[[4'-(Dimethylamino)phenyl]ethynyl]-15-[(4''-nitrophenyl)ethynyl]-10,20-diphenylporphinato]copper(II), S. M. LeCours, C. M. Philips, Julio C. de Paula, and M. J. Therien
Domain organization of Calbindin D28k as determined from the association of six synthetic EF-hand fragments, Sara Linse, Eva Thulin, Lida K. Gifford, and Karin S. Akerfeldt
The OBrO C(2A2)←X(2B1) absorption spectrum, Charles E. Miller, Scott L. Nickolaisen, Joseph S. Francisco, and Stanley P. Sander
The rotational spectrum and molecular properties of bromine dioxide, OBrO, Holger S. P. Muller, Charles E. Miller, and Edward A. Cohen
Synthesis, characterization, and luminescence properties of anthrylpolyamines: an experiment for an integrated, advanced laboratory course, Brian W. Pfennig, Terry L. Newirth, and Scott A. Van Arman
Submissions from 1996
Ca2+-binding stoichiometry of Calbindin D28k as assessed by spectroscopic analyses of synthetic peptide fragments, Karin S. Akerfeldt, Anne N. Coyne, Rosemarie R. Wilk, Eva Thulin, and Sara Linse
Structure and conductance mechanisms of minimalist ion channels, Karin S. Akerfeldt, Paul K. Kienker, and James D. Lear
Nitrile hydratase from Rhodococcus rhodochrous J1 contains a non-corrin cobalt ion with two sulfur ligands, Bridget A. Brennan, Geoffrey Alms, Mark J. Nelson, and Robert C. Scarrow
Protein folding triggered by electron transfer, G. A. Mines, T. Pascher, S. C. Lee, and John P. Chesick
Pressure dependence and metastable state formation in the photolysis of dichlorine monoxide (Cl2O), Scott L. Nickolaisen, Charles E. Miller, Stanley P. Sander, and Michael R. Hand
Circular dichroism and x-ray spectroscopies of Azotobacter vinelandii nitrogenase iron protein. MgATP and MgADP induced protein conformational changes affecting the [4Fe-4S] cluster and characterization of a [2Fe-2S] form, Matthew J. Ryle, William N. Lanzilotta, Lance C. Seefeldt, and Robert C. Scarrow
X-ray spectroscopy of nitrile hydratase at pH 7 and 9, Robert C. Scarrow, Bridget A. Brennan, John G. Cummings, and Haiyong Jin
Submissions from 1995
Ullmann ether reaction involving an alkynyl substrate: a convergent route to a combretastatin intermediate, Frances Rose Blase and Kaustuv Banerjee '92
Synthesis of alpha-unsubstituted aldol adducts utilizing enantiomerically pure beta-keto delta-dioxolane sulfoxides, Frances Rose Blase and H. Le
Aggregation of chlorophyll a probed by resonance light scattering spectroscopy, Julio C. de Paula, John H. Robblee, and R. F. Pasternack
Transient resonance Raman spectroscopy of copper(II) complexes of meso-tetraphenylporphine and meso-tetraphenylchlorin, Julio C. de Paula, V. A. Walters, K. Hall, and J. Lind
Structure and Kinetics of Formation of Catechol Complexes of ferric soybean lipoxygenase-1, Mark J. Nelson, Bridget A. Brennan, D. Bruce Chase, and Robert C. Scarrow
Acetylation of Ferrocene: a Study of the Friedel-Crafts Acylation Mechanism as Measured by HPLC using an Internal Standard, Terry L. Newirth and Nadine Srouji
Asymmetric construction of an advanced F-G-H-ring lactone precursor for the synthesis of penitrem D: tremorgenic indole alkaloids, part 9, Amos B. Smith III, Ernest G. Nolen Jr., Ryuichi Shirai, and Frances Rose Blase
Tremorgenic indole alkaloids. 9. asymmetric construction of an advanced F-G-H-ring lactone precursor for the synthesis of Penitrem D, Amos B. Smith III, Ernest G. Nolen Jr., Ryuichi Shirai, and Frances Rose Blase
Electronic structure of triplet states of zinc(II) tetraphenylporphyrins, V. A. Walters, Julio C. de Paula, B. Jackson, and C. Nutaitis
Submissions from 1994
Synthesis and per-functionalization of heptakis (6-O-carboxymethyl-2, 3-di-O-methyl) cyclomaltoheptaose, Karin S. Akerfeldt and William F. DeGrado
Use of cyanobacteria in the study of the structure and function of photosystem II, Bridgette A. Barry, Renee J. Boerner, and Julio C. de Paula
Spreadsheets in general chemistry: their introduction and application to complex titrations, John P. Chesick
General method for coupling unprotected peptides to Bromocetamido Porphyrin templates, Christin T. Choma, Karen Kaestle, and Karin S. Akerfeldt
Structure-function relationships in the 47-kDa antenna protein and its complex with the reaction center core of photosystem II: insights from resonance Raman spectroscopy and picosecond fluorescence decay kinetics, Julio C. de Paula, A. Liefshitz, S. Hinsley, and W. Lin
X-ray Spectroscopy of the Iron Site in Soybean Lipoxygenase-1: Changes in Coordination upon Oxidation or Addition of Methanol, Robert C. Scarrow, Milton G. Trimitsis, Charles P. Buck, and Geoffrey N. Grove
Submissions from 1993
Synthetic Peptides as Models for Ion Channel Proteins, Karin S. Akerfeldt, James D. Lear, Zelda R. Wasserman, Laura A. Chung, and William F. Degrado
Harmut Michel, Johann Deisenhofer, and Robert Huber, Julio C. de Paula
Three applications of a nitrogen laser pumped dye laser in the undergraduate laboratory: from spectroscopy to photochemistry, Julio C. de Paula, J. Lind, M. Gardner, and K. Walters